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glazenerd

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About glazenerd

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    St. Louis, Mo.
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    Crystalline glaze chemistry. Porcelain, Stoneware, Fritware, 04 Colored Porcelain clay research & formulation.
    Ceramics Monthly Articles: Jan. 2018 Cation Exchange (plasticity), April 2018 SSA Clay Formulation, May 2018 Bloating and Coring.
    Feb. 2019 Ceramics Monthly- Clay Body Shopping Guide
    March 2019 Ceramics Monthly - Porcelain 201
    June 2019 Ceramics Monthly Clay Restoration
    Sept. 2019 Clay Memory
    Oct. 2019 Firing Programs

    Email: optix52@aol.com

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  1. Gen: Gold specks possible pyrite: but not mica- mica would be glassy or white. Pyrite is FeS (sulfur) and judging by your result with 50 local 50 B-mix: you have in excess of 8% iron content. The only issue that makes me doubt pyrite is the dried greenish color: hematite in the presence of calcium will present greenish. The simple test to determine that: iron disulfide (pyrite) will go brown at cone 6- hematite will keep a deep red tint. Alluvial soil is fine grained- sub micron and lower in alumina. If pyrite, doubt you can fire past cone 1-2 without pyroplastic issues. If hematite: then it should handle cone 6 because hematite and magnetite clay runs between 20-24% alumina- iron disulfide runs 15-17%. The test is simple: just put a button of you clay on a tile, scrap whatever and cook it to cone 6. Brown- iron disulfide- low fire. Deep red- hematite. Plasticity- your sample has high sand content which is "tempering" the clay- not the same as plasticity. Tempering comes from the brick industry- used to produce malleability, but not plasticity. (They do not want high shrink values). Plasticity- start with 20% OM4. EX. 200 grams OM4 per 1000 grams local clay. You are hand mixing I assume? If so, it will take 3-5 days before full plasticity will develop. Overdo the plasticizer then you will have the opposite problem of clay fatigue- slumping-folding. Burn a sample to cone 6- confirm what the iron source is: then address formula- cone value. Nerd
  2. Cone 6 stoneware 76% OM4, 14% feldspar, 10% silica. ( This is a plasticity fix only.)
  3. Coleman Porcelain. >Aatdvark Clay is highly rated for Cone 10. Laguna Frost porcelain- cone 6. Any "high white" porcelain will work. Translucency is not a requirement for crystals. Colorants should be 325 mesh. Alumina, titanium dioxide, red iron, copper carb, manganese, cobalt carb. ilumenite, and rutile are commonly used in crystal recipes. Small quantities: very little colorant goes a long way. Nerd
  4. Liam: acid etching usually involves full strength muratic acid with only mild dilution. Typically the PH hovers around 1.5- very corrosive to skin, eyes, and inhalation of fumes can damage lung tissue. Not only requires eye and skin protection, but also respirator for those specific fumes. If left to soak indoors: can rust any metals within a few feet within hours. Seriously bad idea to make that suggestion to a screen name with "hobby" in it. Yes, I play with some potent stuff: but I have the safety equipment, and the training (EPA) to do so. And I dispose of it within recommended guidelines.
  5. By the way- stay far away from acid baths: dangerous if you do not know what you are doing and do not have the proper safety equipment.
  6. In the crystalline world this is called: "Crap." If you do not get results in the initial firing: odds of recovery in a second fire is slim to none. However it is a good lesson of how colorants and oxides disperse in a firing. Notice the large run lines of the cobalt and the white streaks (tin) going down the sidewalls. This is also a good lesson on glaze application. Vertical pieces- 0.65-0.75 grams per square inch. Flat surfaces- 0.45-0.50 grams per square inch. When glaze application is excessive: it will pool and crystallize. A good record none the less: you now know what excessive glaze application looks like. To further explain technical terms: when you open the kiln expecting beautiful crystals and see this: the immediate reaction is "crap." Descriptive on both a chemistry and emotional level.
  7. Notice the streaks running down the side walls? In this case: that is the tin and zinc pooling to the bottom. Lose too much colorant- blotchy crystals. Lose too much zinc- no crystals. In dead center bottom there are too large blotches with raised rims. That is called "boiling" in the crystalline world. It is caused by excessive peak temp; but also common when excessive lithium carb is used in the recipe. Cobalt is reactive to excessive heat and/or excessive flux: boiling is a direct indication of those problems.
  8. Jess: going to turn your results into an educational dissection of results. You have inner and outer growth rings: just need a mild downward adjustment in ramp hold (growth) cycle temps. Do not worry about the crazing at this point. Dial in your peak melt temp, then your growth cycle temps : then adjust silica to control crazing later.RULE 1: only change one parameter at a time when testing crystalline: so you know exactly which change caused what reaction. Final assessment: you did exceptionally well for your first time out with this glaze- be proud.
  9. Actually Mark, your email convinced me to make one more post. The reason I am disconnecting is at the bottom. I cut and pasted this from the Crystalline Glaze forum- to where I just posted it under my user name there. ------------- Actually Gordon, I have been reading about the effects of PH on ionic exchange; in part the theory behind a terra Sig. Norton (M.I.T.) and Lawrence & Buttons (Alfred) did the original studies on slip starting in 1948-1974. Norton actually started the whole sodium silicate/terra sig when he was studying the effects of PH on the water hull. He wrote the "stretched membrane" theory in 1948: the basis of modern slip chemistry. Norton describes the measured effects of sodium silicate in solution: resulting in a particle range from 0.14 to 0.57 microns..or in pottery terms 30,000 mesh. If you are a big terra sig person: first buy Taylor ball clay from a Old Hickory Clay Co. In Kentucky. OM4 has a median particle size of 0.67, and Taylor 0.31. Which means you will get over twice the payload for your efforts. With freight, Taylor will cost you 0.50 cents a lb- but they sell 50lb bags only. Second is an ionic charge trick I will teach you. Lawrence and a Buttons also wrote on the effects of temperature on ionic charge. At 60F, the ionic charge that suspends those fine particles potters want in terra sig drops by 1/3, which directly effects the amount produced. However, at 140F, the ionic charge is at its peak: which means the quality of fine particles held in suspension is much higher- resulting in more yield. The trick: heat the water to 135-140F ( but no higher), add your sodium silicate first- then your Taylor ( or OM4). In 1-2 hours when it cools back to room temp 75 or so. Siphon off the goodies as usual. You now have more sig in two hours than in 24 hours. So remember folks- you heard it here first. As other potters hack the info from this site and add it to theirs and claim a great discovery- you heard it hear first. Enjoy Gordon tom. - was going to make a CM article out of this... But hey. Several recent threads on image theft, cultural theft: but theft of intellectual property is never mentioned.
  10. LT: there are 100 plus references to journals, thesis, books, and other resources on the effects of temp on clay bodies. https://books.google.com/books?id=pQpCDCPqlS4C&pg=PA58&lpg=PA58&dq=W.H.+Sutton;+factors+influencing+the+strength+of+clay+bodies&source=bl&ots=AfkxuypAxo&sig=ACfU3U2W_Zh8NTluxpwvcnIN4zVOWBV3vw&hl=en&sa=X&ved=2ahUKEwjB-_rwj7jiAhUPnq0KHaUpC_YQ6AEwAXoECAQQAQ#v=onepage&q=W.H. Sutton%3B factors influencing the strength of clay bodies&f=false you need to hire a research assistant: I am a little busy. as I have told you in PM before- W.G. Lawrence " Ceramic Science for the Potter." F.H. Norton " Fine Ceramics, Technology and Application". And the book referenced above are the best encapsulated information resources. For the record: I have journal references lying all over the place in my various threads. Feel free to go find them. Long past tired of having post proof every time I make technical posts. Tom
  11. Bill: results from Ougland & Brindley study on heat work. 2192F (1200C) minimum further development of the clay body after this point. Minor decreases in absorption, along with minor increases in glass content. See chart below. Typical cone six ramp hold temperature for maturity. ----------------- --------------------- 2192F (1200C.). Glass 62. Silica 21. Mullite 19 2372F (1300C). Glass 66. Silica 16. Mullite 21 (Ougland & Brindley) Off topic, Ron Roy emailed me: he is doing a work shop nearby in June. Looking forward to seeing my friend. Tom
  12. If anyone ran measured effects of heat work, it would be Orton Sr. He wrote several abstracts for American Ceramic Society, I will nose around and see what I can find. The other source would be Ougland and Brindley from the British Ceramic Society: "Effects of a High Temperature on Kaolinite" I read that abstract, and quoted some of it in my threads. It has since been pulled down, sadly. I have been pricing gradient kilns: and potters gasp at the price of an electric. Keep waiting for a good used one to come along. From my observation pending kiln size: there can be up to 40F difference in a large chamber. Years ago I started mixing my crystalline glazes via PH meter. I raise the PH in cold spots, and lower it in cold spots: works fairly well. I would put conduction up to 2000F, and radiation there after. Edit add: If Edison did not have Telsa: his inventions would have been few. IMOIMO Tom
  13. Sorry Bill, I broke my two cup rule. Never answer questions until I finish the second cup. As I recall: one study was done in Brazil , one in India for their Government, and one in Germany? All three used gradient kilns with 6-10 chambers and 10-15C variation between chambers. The one in India was testing laterite, and reported an exothermic reaction at 2050F. The study in San Paulo? Actually used bars in various thickness 1/4 to 1/2 in a multi chamber gradient kiln: that studied produced the time of heat absorption and release at 2050F: conduction being the focus as I recall. The one out of Germany was studying local materials, and reported the reaction at 2050F. So 2050F spinel to mullite temp has been confirmed numerous times. U of I (Champaign/Urbana) has numerous studies up on their Ceramic Technology site. I posted a link in one of my ramblings somewhere : stoneware study thread I think. They used X-ray diffraction to analyze heat work and the phase changes in potassium and sodium. At 2190F, sodium and potassium are spent- no longer visible. I cannot confirm this: but I suspect this is where the commonly used 2190F peak with hold firing cycle came from. Orton Sr. Did extensive studies back in 1909-1919 range(?) noted in my Nerds Firing Schedule thread. He proposed the 108F ramp speed for several reasons: primarily to burn off inorganic carbons, secondly for heat work purposes. As you well know, cones are based on Segers work, but Orton did the initial testing on calibrated heat work. did I answer them that time, or do I need a third cup? Check my Stoneware study thread, Nerds Firing Schedule thread, and possibly my Porcelain thread. I have links to studies floating all around. I do know some studies are no longer accessible: Wiley Library has been buying them up and archiving them. Tom
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