@PeterH That thread is brilliant thank you!!
Like @tkw954 I was intending to 3D print the master, but using a wax-based low temperature filament. However using water- or acid-soluble filament sounds better, and could hopefully leave minimal contamination.
The master would be a roughly 30cm tall full human figure with limbs and potentially separate fingers (the worst possible for casting essentially). I aim to get only 80% of the way with casting, cracks and damage are okay because I intend to thoroughly rework with more clay by hand. Also, I plan to use a wire armature, which means the mold will need to be at least two parts, but that's a separate challenge..
In the interest of keeping the clay workable, I don't want to subject it to any heat, so I'm considering adding sawdust or structural weakness to the plaster to assist in removal.